Car A/C
Very possibly the reason that the A/C repairman didn't charge the system is the cost of Freon-12. This is what old automotive systems use, and it isn't made anymore due to environmental issues. Thus,the price is now high for remaining stock. In addition, A/C repairmen now face expensive licensing issues and standards, and are loathe to just recharge a slightly leaky system.
If the system has issues, then after fixing it you can either fork out for real Freon-12, convert it to R-134a, or use a "replacement" refrigerant. R-134a is a more modern refrigerant, and does work on older systems providing that the entire system is evacuated first, and all the oil removed. This is hard to do, but essential as the oiling requirements are different for the systems. It also isn't as efficient, so the final result may not cool as well. The replacement refrigerants vary, but many are based on propane. That is a great refrigerant, but of course there is always the issue of what happens if you have a wreck and the propane escapes near an open flame. I have no idea if this is just scare-mongering or if there have been documented issues here. All of this is why people don't jerry-rig leaky old A/C systems like they use to.