It really works! But why?
Most plastic wrap is made of polyethylene. Found in everything from grocery bags and even bulletproof vests, it’s the most commonly used plastic in the world. In plastic wrap, the polymer's molecules are really tight and naturally sticky. But it’s the fact that manufacturers add adhesives that make it cling to other materials. Of course, plastic wrap is also known to create static electricity which leads to the argument for storing it in the freezer. According to The Kitchn, cold air cuts back on static. However, more likely, plastic wrap loses its stickiness in the cold for molecular reasons. "The adhesion between pieces of plastic may be driven by the molecules in the surface re-arranging themselves to form weak chemical bonds," explains Dr. Chad Orzel, Associate Professor of Physics and Astronomy at Union College, "and the lower temperature may inhibit that process a bit." Orzel, author of How to Teach Quantum Physics to Your Dog, admits that he's not an expert in plastic wrap, but in his experience, it could behave like tape. "I know from attempting winter repairs with duct tape that conventional adhesives don't necessarily work well in cold temperatures."
Regardless of what makes it work, if you don’t want to wrestle with unwrapping your plastic wrap, store it in the freezer.
Most plastic wrap is made of polyethylene. Found in everything from grocery bags and even bulletproof vests, it’s the most commonly used plastic in the world. In plastic wrap, the polymer's molecules are really tight and naturally sticky. But it’s the fact that manufacturers add adhesives that make it cling to other materials. Of course, plastic wrap is also known to create static electricity which leads to the argument for storing it in the freezer. According to The Kitchn, cold air cuts back on static. However, more likely, plastic wrap loses its stickiness in the cold for molecular reasons. "The adhesion between pieces of plastic may be driven by the molecules in the surface re-arranging themselves to form weak chemical bonds," explains Dr. Chad Orzel, Associate Professor of Physics and Astronomy at Union College, "and the lower temperature may inhibit that process a bit." Orzel, author of How to Teach Quantum Physics to Your Dog, admits that he's not an expert in plastic wrap, but in his experience, it could behave like tape. "I know from attempting winter repairs with duct tape that conventional adhesives don't necessarily work well in cold temperatures."
Regardless of what makes it work, if you don’t want to wrestle with unwrapping your plastic wrap, store it in the freezer.