explode or burn...
I was translating white papers for B/S/H when they started planning to make home refrigerators with flammable refrigerants.
They did an enormous amount of testing - both in terms of the manufacturing (vent fans and air flow and both sophisticated and mega-simple, fail-safe monitoring systems) as well as shipping, inventory, end-user.
Their engineers knew enough gas was present at the factory for an explosion. They knew enough was present in a delivery wagon on a train or in a truck for an explosion. They were unable, ever, to bring a single, solitary unit to explode with the amount of gas with which it was charged. Just couldn't get the air/gas mixture needed.
But - they (to their shock!) managed to ignite gas jets which burned long enough to set surrounding plastics on fire.
This really, really bothered them. Enough for them to change the composition of the materials, the rear wall and to reroute one capillary tube (at considerable expense).
Had I not been there, I'd have never known of it. It cost B/S/H enormous amounts of money to do it right. I sincerely doubt that the gas in a properly designed fridge, in an of itself can collect in the proper gas/air mixture to explode in the dictionary definition sense of the word. That, however, the plastics used and the awful construction and attention to safety (lack thereof) for which today's Hotpoint is known all contributed to one heck of a fire?
Don't doubt it one bit. That the melting plastic might have released enough explosive gas/es to make an explosion possible? Don't doubt that, either.
Is it possible Hotpoint had such a bad design that a pocket of R-600 managed to reach a gas/air mixture capable of explosion? Sadly, yes, I've seen enough of their trash in the UK to believe they'd make such a mistake.
So - realistically - no, refrigerators don't, all in all, explode. Can they, under certain conditions? Obviously, yes.
Is R-600 therefore a bad choice? Nope. Just Hotpoint.