Bleach Detergent?

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Don't get it.

Why are folks worried about using chlorine bleach in a stainless steel interior dishwasher? We have most of use used chlorine bleach in our stainless steel drum clothes washing machines for many years with no problem. So why would the bleach harm a dishwasher if it's safe in a washing machine?
 
Deborah,

 

Bosch specifically warns NOT to use chlorine bleach in its AXXIS  front loader washer.

 



 

On page 13, see the following:

 

"DO NOT use chlorine bleach in this washing machine."

 

While the manual doesn't explain why, I have read in past forum posts here or elsewhere, that it's because the chlorine bleach could damage the washer's heating element.

 

 

 
 
Also, chlorine bleach can and has caused pitting corrosion of stainless steel. There's an interesting thread somewhere on the internet I read some years ago, in a craft brew site, of an instance where sterilizing stainless steel brewing containers with chlorine bleach resulted in such pitting corrosion to the point where the vessels no longer could hold pressure due to pinhole leaks.

 

What makes stainless steel rust-resistant is a protective chromium oxide layer that forms on exposure to air. This layer is what protects the steel from rusting. The problem with chlorine bleach is that it can remove or compromise the chromium oxide layer and allow corrosion of the steel to occur.

 

In the case of the brewing vessels, I recall that the theory was that the bleach solution was not thoroughly rinsed out, and allowed to remain. As the solution evaporated, droplets of it became more and more concentrated, to the point where the concentrated bleach attacked the protective chromium oxide layer and resulted in the pinhole leaks.

 
 
Also, on page 17 of the Bosch Axxis manual linked above:

 

 

WARNING

 

DO NOT use chlorine bleach in this washing machine.

 

 

CAUTION

 

Decolorants may contain sulphur or chlorine.

These substances can cause parts of the washing machine to corrode. Do not decolorize items of laundry in the washing machine.
 
My 22 year old Asko says not to use chlorine.   I've been using it the entire time I've owned it and have had zero problems.  The heating element isn't even discolored.  Miele also doesn't recommend but again I've been using it...but not on the 190F cycle.
 
I`m wondering if Bosch`s warning against the use of chlorine might have more to do with the aluminum spider than the stainless steel parts.
As I said before stainless steel interior dish washers have always been the preferred design in the EU, long before chlorine free DW detergents came along.
But those were also loaded with waterglass a corrosion inhibitor which liquid chlorine bleach does not contain. Maybe this made all the difference.
 
I think that with FL washers of early generations with stainless steal or aluminium parts EU manufacturers assumed that US people would use chlorine bleach much more frequently (like 10 to 100 times more commonly) and that they would not adjust dosage accordingly to the significantly lower water levels and probably higher temps and just put that disclaimer there to get out of any warranty claims related to that.

Those oxide layers are "fragile" and damage to them can lead to corrosion but as long as there is air around there should be really no danger.
Those oxide layers are atoms thick and reform badicly instantly on contact with air.

A much higher danger - especially with SS - is corrosion by particulates of other corrosive metals getting attached to the material for example during manufacturing.
 
Great post, Alexander. It explains quite well the problem with chlorine and how to avoid it.

 

I was rummaging around my fish pond supplies the other day, and came across a tub of sodium thiosulfate. I used to mix up a concentration of that, and then use a metered siphon to add it to the make up water that runs into the pond from the tap every morning on a timer. However since a few years ago, the local water service changed from elemental chlorine to chloramine, the actual chlorine levels plummeted and I've been able to get by without any thiosulfate usage since.
 
The bleach compartments

in FL washers are super small. You're literally using a couple of tablespoons and by the time the washer fills, it gets diluted and rinsed away. It's not like full-strength bleach is just sitting on the stainless. I could totally see how that could eat away at anything. I've seen so many videos of failing spiders and the inner tub is caked with mutant funk...I think that's what kills the spider, not the bleach. I can't stress how I'm talking about a couple of tablespoons of bleach going in the dishwasher (give or take) at the very moment you start it. I'm not like pouring a whole cup in there or anything. I use so little of the stuff that 1/2 gallon takes me ages to go through and I can barely get through it before it expires.

My FL washer is approaching 15 years old & it would be very difficult for me to go live without a little LCB

I remember growing up, we used Chlorox bleach in our TL washer, and we poured the recommended amount in and it was so STRONG. We always cut way back on the recommended amount because a little of it goes a LONG way and does less damage to fabrics.
 
Just as an aside... salt water can corrode stainless steel, from the chloride ion in salt, which is sodium chloride. The steels with more nickel, like 18-8 or 304, are more resistant to salt water corrosion. 18-8 mean 18% chromium, 8% nickel. Even more resistant to salt water is 316, which is 16% chromium, 10% nickel, and 2% molybdenum. The molybdenum gives it more salt resistance.

 

There are many different types of stainless steel. In broad categories, they might be ferritic (usually magnetic), martensitic (harder, like for knives), precipitation hardening, or austenitic (generally non magnetic unless worked). The 304 and 316 types are austenitic. Most stainless steel knives (for cutting) are martensitic. Most stainless cutlery is austenitic, with the better quality being 304 or 316. It's a complex subject and even two knives made from the same type steel may have different characteristics depending on how they are manufactured.

 

 

 

 
 

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